Nitrophenylamide derivatives of 2,5-diamidopyrroles: structural behaviour, anion binding and colour change signalled deprotonation
Camiolo, Salvatore, Gale, Philip A., Hursthouse, Michael B. and Light, Mark E. (2003) Nitrophenylamide derivatives of 2,5-diamidopyrroles: structural behaviour, anion binding and colour change signalled deprotonation. Organic and Biomolecular Chemistry, 126, (4), 741-744. (doi:10.1039/b210848h).
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Original Publication URL: http://dx.doi.org/10.1039/b210848h
Description/Abstract
Two new 2,5-diamidopyrrole clefts have been synthesized containing 4-nitrophenyl or 3,5-dinitrophenyl groups appended to the amide moieties. The 3,5-dinitrophenyl derivative has been shown to deprotonate in the presence of fluoride which in acetonitrile solution gives rise to a deep blue colour.
| Item Type: | Article |
|---|---|
| Additional Information: | This article was featured on the front cover of Vol 1 Iss. 4 of Organic and Biomolecular Chemistry |
| ISSNs: | 1477-0520 (print) |
| Related URLs: | |
| Keywords: | sensing, anion, chemidosimeter, fluoride |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 13515 |
| Date Deposited: | 14 Dec 2004 |
| Last Modified: | 02 Mar 2012 12:25 |
| Contributors: | Camiolo, Salvatore (Author) Gale, Philip A. (Author) Hursthouse, Michael B. (Author) Light, Mark E. (Author) |
| Date: | 2003 |
| Additional Information: | This article was featured on the front cover of Vol 1 Iss. 4 of Organic and Biomolecular Chemistry |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/13515 |
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