Interaction kinetics of atoms and molecules on carbon nanotube surfaces
Ulbricht, Hendrik (2009) Interaction kinetics of atoms and molecules on carbon nanotube surfaces. [in special issue: Special Issue of Surface Science dedicated to Prof. Dr. Dr. h.c. mult. Gerhard Ertl, Nobel-Laureate in Chemistry 2007] Surface Science, 603, (10-12), 1853-1862. (doi:10.1016/j.susc.2008.09.062).
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We review recent experimental investigations of the interaction of gases with the surface of single-wall carbon nanotube bundles. We discuss thermal desorption spectra of both non-polar and polar adsorbates for low and high coverage. We show experimental results for diffusion processes of Xe along and within carbon nanotube bucky paper material, which is consistent with a recently proposed coupled desorption diffusion (CDD) model. We further discuss details of the interaction of ammonia with carbon nanotube surfaces, including the experimental investigation of the influence of adsorbed ammonia on the electrical transport properties of carbon nanotubes under ultra-high vacuum conditions.
|Digital Object Identifier (DOI):||doi:10.1016/j.susc.2008.09.062|
|Keywords:||thermal desorption spectroscopy, electrical transport measurements, laser induced thermal desorption (LITD) Adsorption kinetics; Surface diffusion; Ammonia; Xenon; Carbon nanotubes|
|Subjects:||Q Science > QC Physics|
|Divisions:||University Structure - Pre August 2011 > School of Physics and Astronomy
|Date Deposited:||14 Apr 2010 08:37|
|Last Modified:||27 Mar 2014 19:05|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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