Bis-cation salt complexation by meso-octamethylcalix[4]pyrrole: linking complexes in solution and in the solid state
Bis-cation salt complexation by meso-octamethylcalix[4]pyrrole: linking complexes in solution and in the solid state
Pyridinium and imidazolium bis-cations are shown to link calix[4]pyrrole anion complexes both in solution and in the solid state. This is accomplished by binding of the bis-cations to the electron-rich bowl shaped cavities formed by two separate calixpyrrole–anion complexes. These resulting sandwich-type structures provide a new way of organising calix[4]pyrrole anion complexes in space.
96
Caltagirone, Claudia
9148afed-6af0-4fcd-b30e-daa3d7765dc0
Bill, Nathan L.
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Gross, Dustin E.
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Light, Mark E.
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Sessler, Jonathan L.
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Gale, Philip A.
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January 2010
Caltagirone, Claudia
9148afed-6af0-4fcd-b30e-daa3d7765dc0
Bill, Nathan L.
92f633c4-0895-46fd-b074-28678ff68585
Gross, Dustin E.
7e100882-efc6-4562-902d-f48fdff01d07
Light, Mark E.
cf57314e-6856-491b-a8d2-2dffc452e161
Sessler, Jonathan L.
d793ea76-a3a2-4ce1-a8d5-aca7d3307fbe
Gale, Philip A.
c840b7e9-6847-4843-91af-fa0f8563d943
Caltagirone, Claudia, Bill, Nathan L., Gross, Dustin E., Light, Mark E., Sessler, Jonathan L. and Gale, Philip A.
(2010)
Bis-cation salt complexation by meso-octamethylcalix[4]pyrrole: linking complexes in solution and in the solid state.
Organic & Biomolecular Chemistry, 8 (1), .
(doi:10.1039/b916113a).
Abstract
Pyridinium and imidazolium bis-cations are shown to link calix[4]pyrrole anion complexes both in solution and in the solid state. This is accomplished by binding of the bis-cations to the electron-rich bowl shaped cavities formed by two separate calixpyrrole–anion complexes. These resulting sandwich-type structures provide a new way of organising calix[4]pyrrole anion complexes in space.
Text
b916113aeprints.pdf
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Published date: January 2010
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Local EPrints ID: 144895
URI: http://eprints.soton.ac.uk/id/eprint/144895
ISSN: 1477-0520
PURE UUID: 8b95c1bc-5c08-41a6-94ac-372b7fbc2167
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Date deposited: 15 Apr 2010 13:00
Last modified: 14 Mar 2024 02:44
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Author:
Claudia Caltagirone
Author:
Nathan L. Bill
Author:
Dustin E. Gross
Author:
Jonathan L. Sessler
Author:
Philip A. Gale
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