Germanium(II) dications stabilized by azamacrocycles and crown ethers

Cheng, Fei, Hector, Andrew L., Levason, William, Reid, Gillian, Webster, Michael and Zhang, Wenjian (2009) Germanium(II) dications stabilized by azamacrocycles and crown ethers. Angewandte Chemie International Edition, 48 (28), 5152-5154. (doi:10.1002/anie.200901247).

Record type: Article

Abstract

A crown for germanium: Neutral aza- and oxamacrocycles enable stabilization of halide-free germanium(II) dications (see structure, Ge teal, N blue, C gray). The resulting structures show a marked dependence upon the denticity, donor type, and ring size of the macrocycle.

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Published date: 5 June 2009

Keywords: cations, crown compounds, germanium, macrocyclic ligands, main-group elements

Organisations: Chemistry

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Identifiers

Local EPrints ID: 145941

URI: http://eprints.soton.ac.uk/id/eprint/145941

DOI: doi:10.1002/anie.200901247

ISSN: 1433-7851

PURE UUID: 35372228-9303-4942-963a-0c1e36895306

ORCID for Andrew L. Hector:

orcid.org/0000-0002-9964-2163

ORCID for William Levason:

orcid.org/0000-0003-3540-0971

ORCID for Gillian Reid:

orcid.org/0000-0001-5349-3468

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Date deposited: 20 Apr 2010 09:23

Last modified: 14 Mar 2024 02:39

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Contributors

Author: Fei Cheng

Author: Andrew L. Hector

Author: William Levason

Author: Gillian Reid

Author: Michael Webster

Author: Wenjian Zhang

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