Preparation and structure of the unique silicon(iv) cation [SiF3(Me3tacn)]+

Cheng, Fei, Hector, Andrew L., Levason, William, Reid, Gillian, Webster, Michael and Zhang, Wenjian (2009) Preparation and structure of the unique silicon(iv) cation [SiF3(Me3tacn)]+. Chemical Communications, (11), 1334-1336. (doi:10.1039/b822236c).

Record type: Article

Abstract

The trifluorosilicon(IV) cation [SiF3(Me3tacn)]+, isolated as salts with [SiF5]-, [B{3,5-(CF3)2C6H3}4]- or Cl-, is obtained by reaction of SiF4 with Me3tacn under anhydrous conditions, and compared with the tetrafluoro complexes [SiF4(tmeda)] and [SiF4{2-Me2N(CH2)2NMe(CH2)2NMe2(CH2Cl)}][SiF5] obtained with the acyclic di- and tri-amines.

This record has no associated files available for download.

More information

Published date: March 2009

Learn more about Chemistry research

Identifiers

Local EPrints ID: 145945

URI: http://eprints.soton.ac.uk/id/eprint/145945

DOI: doi:10.1039/b822236c

ISSN: 1359-7345

PURE UUID: 828ba90d-ee1e-4890-b49c-e760c3c85c4d

ORCID for Andrew L. Hector:

orcid.org/0000-0002-9964-2163

ORCID for William Levason:

orcid.org/0000-0003-3540-0971

ORCID for Gillian Reid:

orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 20 Apr 2010 09:55

Last modified: 14 Mar 2024 02:39

Export record

Altmetrics

Share this record

Share this on Facebook Share this on Twitter Share this on Weibo

Contributors

Author: Fei Cheng

Author: Andrew L. Hector

Author: William Levason

Author: Gillian Reid

Author: Michael Webster

Author: Wenjian Zhang

Download statistics

Downloads from ePrints over the past year. Other digital versions may also be available to download e.g. from the publisher's website.

View more statistics

Library staff additional information