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mu-1,2-Bis(diphenylphosphino)ethane-kappa P-2 : P-bis[trichloridogallium(III)]

mu-1,2-Bis(diphenylphosphino)ethane-kappa P-2 : P-bis[trichloridogallium(III)]
mu-1,2-Bis(diphenylphosphino)ethane-kappa P-2 : P-bis[trichloridogallium(III)]
The centrosymmetric molecule of the title compound, [(GaCl3)2(C26H24P2)] or [(GaCl3)2{[mu]-Ph2P(CH2)2PPh2}], consists of two pseudo-tetrahedral Ga centres coordinated by three Cl atoms [Ga-Cl = 2.1608 (8)-2.1648 (8) Å] and bridged by the diphosphane ligand [Ga-P = 2.3854 (8) Å].
m1761-[9pp]
Cheng, F.
5efb5dbd-d284-4e80-a3f7-5cffb3ff24fb
Hector, A.L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Zhang, W.
1f80ac5e-d4c2-4720-b19e-be700cd411e7
Cheng, F.
5efb5dbd-d284-4e80-a3f7-5cffb3ff24fb
Hector, A.L.
f19a8f31-b37f-4474-b32a-b7cf05b9f0e5
Levason, W.
e7f6d7c7-643c-49f5-8b57-0ebbe1bb52cd
Reid, G.
37d35b11-40ce-48c5-a68e-f6ce04cd4037
Webster, M.
f26c6e36-cb2e-486e-b2ed-b0d25a3a71f7
Zhang, W.
1f80ac5e-d4c2-4720-b19e-be700cd411e7

Cheng, F., Hector, A.L., Levason, W., Reid, G., Webster, M. and Zhang, W. (2007) mu-1,2-Bis(diphenylphosphino)ethane-kappa P-2 : P-bis[trichloridogallium(III)]. Acta Crystallographica Section E: Structure Reports Online, 63 (6), m1761-[9pp]. (doi:10.1107/S1600536807024592).

Record type: Article

Abstract

The centrosymmetric molecule of the title compound, [(GaCl3)2(C26H24P2)] or [(GaCl3)2{[mu]-Ph2P(CH2)2PPh2}], consists of two pseudo-tetrahedral Ga centres coordinated by three Cl atoms [Ga-Cl = 2.1608 (8)-2.1648 (8) Å] and bridged by the diphosphane ligand [Ga-P = 2.3854 (8) Å].

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More information

Published date: 2007
Organisations: Chemistry

Identifiers

Local EPrints ID: 146995
URI: http://eprints.soton.ac.uk/id/eprint/146995
PURE UUID: 73bf9e4d-7b13-4bd6-8011-aa0110b3fdb6
ORCID for A.L. Hector: ORCID iD orcid.org/0000-0002-9964-2163
ORCID for W. Levason: ORCID iD orcid.org/0000-0003-3540-0971
ORCID for G. Reid: ORCID iD orcid.org/0000-0001-5349-3468

Catalogue record

Date deposited: 07 Jun 2010 10:45
Last modified: 14 Mar 2024 02:39

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Contributors

Author: F. Cheng
Author: A.L. Hector ORCID iD
Author: W. Levason ORCID iD
Author: G. Reid ORCID iD
Author: M. Webster
Author: W. Zhang

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