Synthesis and diastereoselective Diels–Alder reactions of homochiral C2-symmetric butane-1,2-diacetal-based 1,3-dienes


Linclau, Bruno, Clarke, Philip J. and Light, Mark E. (2009) Synthesis and diastereoselective Diels–Alder reactions of homochiral C2-symmetric butane-1,2-diacetal-based 1,3-dienes. Tetrahedron Letters, 50, (51), 7144-7147. (doi:10.1016/j.tetlet.2009.10.015).

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Description/Abstract

The C2-symmetric, butane diacetal (BDA) auxiliary-based dienes 2 and 3 are described, which display moderate to excellent diastereoselectivities in Diels–Alder reactions with a range of dienophiles under thermal and Lewis acid-catalysed conditions.

Item Type: Article
ISSNs: 0040-4039 (print)
Subjects: Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
Item ID: 147901
Date Deposited: 27 Apr 2010 08:22
Last Modified: 02 Mar 2012 12:35
Contributors: Linclau, Bruno (Author)
Clarke, Philip J. (Author)
Light, Mark E. (Author)
Date: 23 December 2009
Status: Published
URI: http://eprints.soton.ac.uk/id/eprint/147901

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