Bimetallic Ru–Sn nanoparticle catalysts for the solvent-free selective hydrogenation of 1,5,9-cyclododecatriene to cyclododecene
Adams, Richard D., Boswell, Erin M., Captain, Burjor, Hungria, Ana B., Midgley, Paul A., Raja, Robert and Thomas, John Meurig (2007) Bimetallic Ru–Sn nanoparticle catalysts for the solvent-free selective hydrogenation of 1,5,9-cyclododecatriene to cyclododecene. Angewandte Chemie International Edition, 46, (43), 8182-8185. (doi:10.1002/anie.200702274).
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Description/Abstract
Tin(n)y catalysts: Bimetallic RuSn supported nanoparticle catalysts (see picture; Ru green, Sn blue, O red), prepared from the carbonyl-cluster precursors [Ru4(4-SnPh)2(-SnPh2)4-x(CO)12-x] (x=0, 2, 3, 4) are shown to be active catalysts for the highly selective hydrogenation of 1,5,9-cyclododecatriene to cyclododecene under mild conditions.
| Item Type: | Article |
|---|---|
| ISSNs: | 1433-7851 (print) 1521-3773 (electronic) |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 148297 |
| Date Deposited: | 03 Jun 2010 10:45 |
| Last Modified: | 01 Jun 2011 07:45 |
| Contributors: | Adams, Richard D. (Author) Boswell, Erin M. (Author) Captain, Burjor (Author) Hungria, Ana B. (Author) Midgley, Paul A. (Author) Raja, Robert (Author) Thomas, John Meurig (Author) |
| Date: | 20 September 2007 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/148297 |
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