Ultraviolet photolysis of HOCl: REMPI measurement of the relative population of chlorine atom (P-2) spin-orbit states


Bell, A.J., Boggis, S.A., Dyke, J.M., Frey, J.G., Richter, R., Shaw, N. and Tabrizchi, M. (1994) Ultraviolet photolysis of HOCl: REMPI measurement of the relative population of chlorine atom (P-2) spin-orbit states. Journal of the Chemical Society, Faraday Transactions, 90, (1), 17-21. (doi:10.1039/FT9949000017).

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Original Publication URL: http://dx.doi.org/10.1039/FT9949000017

Description/Abstract

The nascent chlorine atom (P-2) relative spin-orbit state population resulting from UV photolysis of HOCl has been measured by resonance-enhanced multiphoton ionization (REMPI) in single laser experiments. The ratio of (0.30 +/- 0.07) for Cl*:Cl has been obtained, indicating a stronger preference for production of ground-state Cl(P-2(3/2)) than expected from statistical weights. Also, the Cl+ arrival-time spectra show that most of the energy available in the photolysis is converted into kinetic energy of the photofragments.

Item Type: Article
Related URLs:
Subjects: Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 15925
Date Deposited: 14 Jun 2005
Last Modified: 27 Mar 2014 18:06
URI: http://eprints.soton.ac.uk/id/eprint/15925

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