Bell, A.J., Boggis, S.A., Dyke, J.M., Frey, J.G., Richter, R., Shaw, N. and Tabrizchi, M.
Ultraviolet photolysis of HOCl: REMPI measurement of the relative population of chlorine atom (P-2) spin-orbit states.
Journal of the Chemical Society, Faraday Transactions, 90, (1), . (doi:10.1039/FT9949000017).
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The nascent chlorine atom (P-2) relative spin-orbit state population resulting from UV photolysis of HOCl has been measured by resonance-enhanced multiphoton ionization (REMPI) in single laser experiments. The ratio of (0.30 +/- 0.07) for Cl*:Cl has been obtained, indicating a stronger preference for production of ground-state Cl(P-2(3/2)) than expected from statistical weights. Also, the Cl+ arrival-time spectra show that most of the energy available in the photolysis is converted into kinetic energy of the photofragments.
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