Ultraviolet photolysis of HOCl: REMPI measurement of the relative population of chlorine atom (P-2) spin-orbit states
Bell, A.J., Boggis, S.A., Dyke, J.M., Frey, J.G., Richter, R., Shaw, N. and Tabrizchi, M. (1994) Ultraviolet photolysis of HOCl: REMPI measurement of the relative population of chlorine atom (P-2) spin-orbit states. Journal of the Chemical Society, Faraday Transactions, 90, (1), 17-21. (doi:10.1039/FT9949000017).
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Description/Abstract
The nascent chlorine atom (P-2) relative spin-orbit state population resulting from UV photolysis of HOCl has been measured by resonance-enhanced multiphoton ionization (REMPI) in single laser experiments. The ratio of (0.30 +/- 0.07) for Cl*:Cl has been obtained, indicating a stronger preference for production of ground-state Cl(P-2(3/2)) than expected from statistical weights. Also, the Cl+ arrival-time spectra show that most of the energy available in the photolysis is converted into kinetic energy of the photofragments.
| Item Type: | Article |
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| Related URLs: | |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 15925 |
| Date Deposited: | 14 Jun 2005 |
| Last Modified: | 25 Apr 2013 10:00 |
| Contributors: | Bell, A.J. (Author) Boggis, S.A. (Author) Dyke, J.M. (Author) Frey, J.G. (Author) Richter, R. (Author) Shaw, N. (Author) Tabrizchi, M. (Author) |
| Date: | 1994 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/15925 |
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