Excited vibrational-states near dissociation in weakly bound triatomic systems


Frey, J.G. (1983) Excited vibrational-states near dissociation in weakly bound triatomic systems. Chemical Physics Letters, 102, (5), 421-424. (doi:10.1016/0009-2614(83)87436-3).

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Description/Abstract

The vibrational motion of a weakly bound M3 complex is investigated using hyperspherical coordinates and an adiabatic separation of the radial and angular motions within the molecule. It is shown that the vibrational energy levels near dissociation correlate to an M atom orbiting about a rotating M2 core. Application is made to the neon trimer assuming an approximate pairwise additive potential.

Item Type: Article
Related URLs:
Subjects: Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 15952
Date Deposited: 15 Jun 2005
Last Modified: 27 Mar 2014 18:06
URI: http://eprints.soton.ac.uk/id/eprint/15952

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