Combinatorial characterisation of mixed conducting perovskites

Rossiny, Jeremy C. H., Julis, Jennifer, Fearn, Sarah, Kilner, John A., Zhang, Yong, Chen, Lifeng, Yang, Shoufeng and Evans, Julian R. G. (2008) Combinatorial characterisation of mixed conducting perovskites. Solid State Ionics, 179, (21-26), 1085-1089. (doi:10.1016/j.ssi.2008.01.098).


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One of the most common types of structure which displays Mixed Electronic Ionic Conductivity is the ABO3 perovskite. The perovskite structure defines a very large range of possible oxide compositions and thus, for screening as potential SOFC cathodes, new methods must be used to obtain a complete picture of these MIEC materials. Combinatorial methods offer a route to identify the major trends in functional properties prior to full scale experiment. The system La1 ? xSrxCo1 ? y ? zMnyFezO3 + ? (LSCMF) has been synthesised by combinatorial methods using a robot ink-dip printer. A systematic set of experiments was performed to characterise the trends in crystal structure, and non-stoichiometry with composition. It is the first time that this LSCMF pseudo-ternary has been measured with a 10% B-site substitution of cobalt, manganese and iron

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/j.ssi.2008.01.098
Additional Information: Proceedings of the 16th International Conference on Solid State Ionics, Shanghai, China, 1-6 Jul, 2007
ISSNs: 0167-2738
Keywords: cathode, SOFC, combinatorial, LSM, LSC
Subjects: T Technology > T Technology (General)
Q Science > Q Science (General)
Divisions : University Structure - Pre August 2011 > School of Engineering Sciences > Engineering Materials & Surface Engineering
ePrint ID: 165023
Accepted Date and Publication Date:
September 2008Published
Date Deposited: 08 Oct 2010 08:12
Last Modified: 31 Mar 2016 13:29

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