Dimeric supramolecular motifs of two carboxylate-guanidinium compounds


Ashiq, Muhammad I., Hussain, Ishtiaq, Dixon, Sally, Light, Mark Edward and Kilburn, Jeremy D. (2010) Dimeric supramolecular motifs of two carboxylate-guanidinium compounds. Acta Crystallographica Section C. Crystal Structure Communications, 66, (9), 455-458. (doi:10.1107/S0108270110029252).

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Description/Abstract

The structures of N-benzyl-N'-{6-[(4 carboxylatobenzyl)aminocarbonyl]-2-pyridylmethyl}guanidinium, C23H23N5O3, (I), and N-[2-(benzylaminocarbonyl)ethyl]-N'-{6-[(4-carboxylatobenzyl)aminocarbonyl]-2-pyridylmethyl}guanidinium monohydrate, C26H28N6O4·H2O, (II), both form three-dimensional supramolecular hydrogen-bonded networks based on a dimeric primary synthon involving carboxylate-guanidinium linkages. The differences in the geometries and hydrogen-bonding connectivities are driven by the additional methylpropionamide group and water of crystallization of (II)

Item Type: Article
ISSNs: 0108-2701
Subjects: Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
Item ID: 176343
Date Deposited: 07 Mar 2011 11:25
Last Modified: 24 Aug 2012 02:03
Contributors: Ashiq, Muhammad I. (Author)
Hussain, Ishtiaq (Author)
Dixon, Sally (Author)
Light, Mark Edward (Author)
Kilburn, Jeremy D. (Author)
Date: 4 August 2010
Status: Published
URI: http://eprints.soton.ac.uk/id/eprint/176343

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