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Characterization of a zinc-cerium flow battery

Characterization of a zinc-cerium flow battery
Characterization of a zinc-cerium flow battery
The performance of a divided, parallel-plate zinc–cerium redox flow battery using methanesulfonic acid electrolytes was studied. Eight two and three-dimensional electrodes were tested under both constant current density and constant cell voltage discharge. Carbon felt and the three-dimensional platinised titanium mesh electrodes exhibited superior performance over the 2-dimensional electrodes. The charge and discharge characteristics of the redox flow battery were studied under different operating conditions and Zn/Ce reactant, as well as methansulfonic acid concentration. The cell performance improved at higher operating temperatures and faster electrolyte flow velocities. The number of possible cycles increased at reduced states of charge. During 15 min charge/discharge per cycle experiment, 57 cycles were obtained and the zinc reaction was found to be the limiting process during long term operation.
cerium, energy storage, methanesulfonic acid, redox flow battery, zinc
0378-7753
5174-5185
Leung, P.K.
0a85d602-5141-41e5-8dbd-12873d5b9d4a
Ponce de Leon, C.
508a312e-75ff-4bcb-9151-dacc424d755c
Low, C.T.J.
e993d0ca-2b64-424b-9535-20bc8b78415f
Shah, A.A.
5c43ac37-c4a7-4256-88ef-8c427886b924
Walsh, F.C.
309528e7-062e-439b-af40-9309bc91efb2
Leung, P.K.
0a85d602-5141-41e5-8dbd-12873d5b9d4a
Ponce de Leon, C.
508a312e-75ff-4bcb-9151-dacc424d755c
Low, C.T.J.
e993d0ca-2b64-424b-9535-20bc8b78415f
Shah, A.A.
5c43ac37-c4a7-4256-88ef-8c427886b924
Walsh, F.C.
309528e7-062e-439b-af40-9309bc91efb2

Leung, P.K., Ponce de Leon, C., Low, C.T.J., Shah, A.A. and Walsh, F.C. (2011) Characterization of a zinc-cerium flow battery. Journal of Power Sources, 196 (11), 5174-5185. (doi:10.1016/j.jpowsour.2011.01.095).

Record type: Article

Abstract

The performance of a divided, parallel-plate zinc–cerium redox flow battery using methanesulfonic acid electrolytes was studied. Eight two and three-dimensional electrodes were tested under both constant current density and constant cell voltage discharge. Carbon felt and the three-dimensional platinised titanium mesh electrodes exhibited superior performance over the 2-dimensional electrodes. The charge and discharge characteristics of the redox flow battery were studied under different operating conditions and Zn/Ce reactant, as well as methansulfonic acid concentration. The cell performance improved at higher operating temperatures and faster electrolyte flow velocities. The number of possible cycles increased at reduced states of charge. During 15 min charge/discharge per cycle experiment, 57 cycles were obtained and the zinc reaction was found to be the limiting process during long term operation.

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Published date: 1 June 2011
Keywords: cerium, energy storage, methanesulfonic acid, redox flow battery, zinc
Organisations: Engineering Mats & Surface Engineerg Gp

Identifiers

Local EPrints ID: 184975
URI: http://eprints.soton.ac.uk/id/eprint/184975
ISSN: 0378-7753
PURE UUID: d6fdb568-06d5-41dc-a3c2-3f8577f2549e
ORCID for C. Ponce de Leon: ORCID iD orcid.org/0000-0002-1907-5913

Catalogue record

Date deposited: 09 May 2011 12:44
Last modified: 15 Mar 2024 03:22

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Contributors

Author: P.K. Leung
Author: C.T.J. Low
Author: A.A. Shah
Author: F.C. Walsh

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