Total spontaneous resolution of a cyanoguanidine showing only conformational chirality
Cunningham, I. D., Coles, S. J. and Hursthouse, M. B. (2000) Total spontaneous resolution of a cyanoguanidine showing only conformational chirality. Chemical Communications, (1), 61-62. (doi: 10.1039/a907518f)
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Description/Abstract
The total spontaneous resolution of N-(4-chlorophenyl)-N'-cyano-N,N",N"-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | absolute asymmetric-synthesis, solid-state, crystal environment, amide |
| Related URLs: | http://www.rsc.org/Publishing/...i=a907518f |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 18851 |
| URI: | http://eprints.soton.ac.uk/id/eprint/18851 |
| Deposited On: | 20 Dec 2005 |
| Last Modified: | 02 Mar 2012 13:47 |
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