Total spontaneous resolution of a cyanoguanidine showing only conformational chirality
Cunningham, I. D., Coles, S. J. and Hursthouse, M. B. (2000) Total spontaneous resolution of a cyanoguanidine showing only conformational chirality. Chemical Communications, (1), 61-62. (doi: 10.1039/a907518f).
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The total spontaneous resolution of N-(4-chlorophenyl)-N'-cyano-N,N",N"-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.
|Keywords:||absolute asymmetric-synthesis, solid-state, crystal environment, amide|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||20 Dec 2005|
|Last Modified:||02 Mar 2012 13:47|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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