Total spontaneous resolution of a cyanoguanidine showing only conformational chirality


Cunningham, I. D., Coles, S. J. and Hursthouse, M. B. (2000) Total spontaneous resolution of a cyanoguanidine showing only conformational chirality. Chemical Communications, (1), 61-62. (doi: 10.1039/a907518f).

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Description/Abstract

The total spontaneous resolution of N-(4-chlorophenyl)-N'-cyano-N,N",N"-trimethylguanidine, a compound which shows only conformational chirality, is described; variable temperature NMR experiments show that rotation of the dimethylamino group is rapid in solution at room temperature as is conformer interconversion by rotation of the arylmethylamino group.

Item Type: Article
Related URLs:
Keywords: absolute asymmetric-synthesis, solid-state, crystal environment, amide
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18851
Date Deposited: 20 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18851

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