Synthesis and properties of thallium(III) periodate


Binsted, N., Hector, A. L. and Levason, W. (2000) Synthesis and properties of thallium(III) periodate. Inorganica Chimica Acta, 298, (1), 116-119. (doi:10.1016/S0020-1693(99)00427-2).

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Description/Abstract

The reaction of [T1(H2O)(6)](3 +) with H5IO6 in aqueous acid solution over a range Tl-5(IO6)(3), which has been characterised by analysis, IR and UV-Vis spectroscopy The compound is amorphous, but I K- and Tl L-III edge EXAFS studies identify IO6 and TlO6 as the structural units present and a possible structure is proposed. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. The Tl(III)-IO6 system is compared with literature data on gallium and indium periodate complexes. (C) 2000 Elsevier Science S.A. All rights reserved.

Item Type: Article
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Keywords: thallium periodate, exafs complexes
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18880
Date Deposited: 03 Jan 2006
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18880

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