The synthesis and characterisation of bis(phenylpyridylphosphino)ethane
The synthesis and characterisation of bis(phenylpyridylphosphino)ethane
A novel synthesis has been devised for the preparation of unsymmetrical phosphine substituted derivatives of bis(diphenylphosphino)ethane [dppe]. The title ligand has been prepared in a two step procedure from dppe. A palladium(II) complex of this new ligand has been prepared and characterised by single crystal X-ray diffraction.
pyridine, pyridylphosphines, ligand
ray crystal-structures, complex, dippe=1, 2-bis(diisopropylphosphino)ethane, phosphines, 2-pyridyl, chemistry, ligands
103-107
Butler, I. R.
d8a1fc6e-b2be-42fe-b655-c65b803c8903
Licence, P.
725c4e8d-aa44-4663-8fbf-6b6e1f98305e
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
25 March 2000
Butler, I. R.
d8a1fc6e-b2be-42fe-b655-c65b803c8903
Licence, P.
725c4e8d-aa44-4663-8fbf-6b6e1f98305e
Coles, S. J.
503a9d9c-0380-4fcd-ad31-cd329255c08e
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Butler, I. R., Licence, P., Coles, S. J. and Hursthouse, M. B.
(2000)
The synthesis and characterisation of bis(phenylpyridylphosphino)ethane.
Journal of Organometallic Chemistry, 598 (1), .
(doi:10.1016/S0022-328X(99)00683-X).
Abstract
A novel synthesis has been devised for the preparation of unsymmetrical phosphine substituted derivatives of bis(diphenylphosphino)ethane [dppe]. The title ligand has been prepared in a two step procedure from dppe. A palladium(II) complex of this new ligand has been prepared and characterised by single crystal X-ray diffraction.
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More information
Published date: 25 March 2000
Keywords:
pyridine, pyridylphosphines, ligand
ray crystal-structures, complex, dippe=1, 2-bis(diisopropylphosphino)ethane, phosphines, 2-pyridyl, chemistry, ligands
Identifiers
Local EPrints ID: 18890
URI: http://eprints.soton.ac.uk/id/eprint/18890
ISSN: 0022-328X
PURE UUID: 0ba61e31-2813-4a40-b01e-7c72eada94ab
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Date deposited: 05 Jan 2006
Last modified: 15 Mar 2024 06:08
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Author:
I. R. Butler
Author:
P. Licence
Author:
S. J. Coles
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