The synthesis and characterisation of bis(phenylpyridylphosphino)ethane

Butler, I. R., Licence, P., Coles, S. J. and Hursthouse, M. B. (2000) The synthesis and characterisation of bis(phenylpyridylphosphino)ethane. Journal of Organometallic Chemistry, 598, (1), 103-107. (doi:10.1016/S0022-328X(99)00683-X).


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A novel synthesis has been devised for the preparation of unsymmetrical phosphine substituted derivatives of bis(diphenylphosphino)ethane [dppe]. The title ligand has been prepared in a two step procedure from dppe. A palladium(II) complex of this new ligand has been prepared and characterised by single crystal X-ray diffraction.

Item Type: Article
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Keywords: pyridine, pyridylphosphines, ligand ray crystal-structures, complex, dippe=1,2-bis(diisopropylphosphino)ethane, phosphines, 2-pyridyl, chemistry, ligands
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18890
Date Deposited: 05 Jan 2006
Last Modified: 06 Aug 2015 02:18

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