Structure of uranium(VI) oxide dihydrate, UO3. 2H(2)O; synthetic meta-schoepite (UO2)(4)O(OH)(6). 5H(2)O


Weller, M. T., Light, M. E. and Gelbrich, T. (2000) Structure of uranium(VI) oxide dihydrate, UO3. 2H(2)O; synthetic meta-schoepite (UO2)(4)O(OH)(6). 5H(2)O. Acta Crystallographica Section B-Structural Science, 56, 577-583. (doi:10.1107/S0108768199016559).

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Description/Abstract

The structure of uranium oxide dihydrate, also known as meta-schoepite (UO2)(4)O(OH)(6). 5H(2)O, has been determined from a synthetic single crystal. The structure, at 150 K, space group Pbcn, lattice constants a = 14.6861 (4), b = 13.9799 (3) and c = 16.7063 (5) Angstrom, consists of layers of stoichiometry (UO2)(4)O(OH)(6), formed from edge-sharing UO7 pentagonal bipyramids, interleaved with hydrogen-bonded water molecules. Three of the layer hydroxyl groups are linked through hydrogen bonding to single water molecules and the three remaining OH units form interactions with water molecules that each act as acceptors in two hydrogen bonds. One of the water molecules in the inter-layer region is disordered over two symmetry-related sites and forms hydrogen-bonded interactions only within the layer and with the uranyl O atoms. The relationship of the structure of meta-schoepite to that of schoepite is discussed in detail.

Item Type: Article
Related URLs:
Keywords: crystal-structure, parameters
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18900
Date Deposited: 03 Jan 2006
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18900

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