Solid-phase synthesis of cyclic sulfonamides employing a ring-closing metathesis-cleavage strategy


Brown, R. C. D., Castro, J. L. and Moriggi, J. D. (2000) Solid-phase synthesis of cyclic sulfonamides employing a ring-closing metathesis-cleavage strategy. Tetrahedron Letters, 41, (19), 3681-3685. (doi:10.1016/S0040-4039(00)00442-1).

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Description/Abstract

Ring-closing olefin metathesis using the Grubbs catalyst was applied to the cyclisative release of resin-bound sulfonamides. Flexible linkers apparently facilitated the cyclisation-leavage, allowing a number of novel cyclic sulfonamides to be prepared in good yields using catalytic amounts of the Grubbs catalyst.

Item Type: Article
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Keywords: ring-closing metathesis, solid-phase synthesis, sulfonamides, linkers organic-synthesis, olefin metathesis, support, oligosaccharides, heterocycles, cyclization
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18909
Date Deposited: 15 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18909

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