Solid-phase extraction of technetium-amine complexes onto C-18 silica and its application to the isolation of Tc-99
Warwick, P. E., Croudace, I. W. and Howard, A. G. (2000) Solid-phase extraction of technetium-amine complexes onto C-18 silica and its application to the isolation of Tc-99. Analytical Chemistry, 72, (16), 3960-3963. (doi:10.1021/ac991457y).
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The extraction of Tc-tripentylamine complexes onto C-18 silica solid-phase extraction columns is evaluated for the selective removal of Tc-99 from other isotopes. The Tc-amine complex-is quantitatively extracted from sulfuric acid and can be recovered from the column by elution with dilute alkali. A clean separation of Tc from all likely contaminants, including Ru, is achieved showing that C-18 silica solid-phase extraction columns are a viable and attractive alternative to the solvent extraction of Tc-99.
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||17 Jan 2006|
|Last Modified:||06 Aug 2015 02:18|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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