Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework
Watson, F. C. and Kilburn, J. D. (2000) Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework. Tetrahedron Letters, 41, (52), 10341-10345. (doi:10.1016/S0040-4039(00)01859-1).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(00)01859-1
Description/Abstract
Radical cascade cyclisation of methylenecyclopropyl cyclohexanone adducts, using samarium diiodide to generate an initial ketyl radical, provide a short route to tricyclic ethers, and the stereochemical outcome can be influenced by the solvent used for the reaction.
| Item Type: | Article |
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| Related URLs: | |
| Keywords: | methylenecyclopropane, samarium diiodide, cascade radical cyclisation cyclization reactions, iodide |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 18918 |
| Date Deposited: | 15 Dec 2005 |
| Last Modified: | 01 Jun 2011 06:12 |
| Contributors: | Watson, F. C. (Author) Kilburn, J. D. (Author) |
| Date: | 23 December 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/18918 |
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