Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework


Watson, F. C. and Kilburn, J. D. (2000) Samarium diiodide mediated cascade radical cyclisations-synthesis of the eudesmane tricyclic framework. Tetrahedron Letters, 41, (52), 10341-10345. (doi:10.1016/S0040-4039(00)01859-1).

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Description/Abstract

Radical cascade cyclisation of methylenecyclopropyl cyclohexanone adducts, using samarium diiodide to generate an initial ketyl radical, provide a short route to tricyclic ethers, and the stereochemical outcome can be influenced by the solvent used for the reaction.

Item Type: Article
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Keywords: methylenecyclopropane, samarium diiodide, cascade radical cyclisation cyclization reactions, iodide
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18918
Date Deposited: 15 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18918

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