Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of Rh(CO)(2)Cl (2)


Newton, M. A., Bennett, R. A., Smith, R. D., Bowker, M. and Evans, J. (2000) Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of Rh(CO)(2)Cl (2). Chemical Communications, (17), 1677-1678. (doi: 10.1039/b003782f).

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Description/Abstract

Room temperature adsorption of [Rh(CO)(2)Cl](2) on TiO2[110] is investigated using Scanning Tunnelling Microscopy (STM) which reveals the formation of nanoparticles that coexist with the mono-disperse Rh(CO)(2)Cl species; the spatial distribution of these particles indicates that nanoparticle formation occurs principally at step edges.

Item Type: Article
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Keywords: geminal dicarbonyl, co, no, tio2(110), adsorbates, catalysts, chlorine, surface, stm
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18920
Date Deposited: 20 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18920

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