Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of Rh(CO)(2)Cl (2)
Newton, M. A., Bennett, R. A., Smith, R. D., Bowker, M. and Evans, J. (2000) Room temperature formation of rhodium nanoparticles on TiO2 110 via metalorganic chemical-vapour deposition (MOCVD) of Rh(CO)(2)Cl (2). Chemical Communications, (17), 1677-1678. (doi: 10.1039/b003782f)
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Description/Abstract
Room temperature adsorption of [Rh(CO)(2)Cl](2) on TiO2[110] is investigated using Scanning Tunnelling Microscopy (STM) which reveals the formation of nanoparticles that coexist with the mono-disperse Rh(CO)(2)Cl species; the spatial distribution of these particles indicates that nanoparticle formation occurs principally at step edges.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | geminal dicarbonyl, co, no, tio2(110), adsorbates, catalysts, chlorine, surface, stm |
| Related URLs: | http://www.rsc.org/Publishing/...i=b003782f |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 18920 |
| URI: | http://eprints.soton.ac.uk/id/eprint/18920 |
| Deposited On: | 20 Dec 2005 |
| Last Modified: | 01 Jun 2011 12:01 |
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