RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure


Henry, P. F., Hughes, R. W., Ward, S. C. and Weller, M. T. (2000) RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure. Chemical Communications, (19), 1959-1960. (doi: 10.1039/b006429g).

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Description/Abstract

The sky blue RbCuPO4-ABW is the first reported maximum copper (framework ratio 1:1) zeotype framework, consisting of alternating PO4 and flattened CuO4 (Cu-O 1.89-1.95 Angstrom) tetrahedra; a second metastable very pale green-blue phase can also be produced by quenching, with conversion to the purely four-coordinate copper material accomplished by application of slight mechanical pressure.

Item Type: Article
Related URLs:
Keywords: zeolite abw, phases
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18930
Date Deposited: 20 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18930

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