RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure
Henry, P. F., Hughes, R. W., Ward, S. C. and Weller, M. T. (2000) RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure. Chemical Communications, (19), 1959-1960. (doi: 10.1039/b006429g)
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Description/Abstract
The sky blue RbCuPO4-ABW is the first reported maximum copper (framework ratio 1:1) zeotype framework, consisting of alternating PO4 and flattened CuO4 (Cu-O 1.89-1.95 Angstrom) tetrahedra; a second metastable very pale green-blue phase can also be produced by quenching, with conversion to the purely four-coordinate copper material accomplished by application of slight mechanical pressure.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | zeolite abw, phases |
| Related URLs: | http://www.rsc.org/Publishing/...i=b006429g |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 18930 |
| URI: | http://eprints.soton.ac.uk/id/eprint/18930 |
| Deposited On: | 20 Dec 2005 |
| Last Modified: | 01 Jun 2011 17:07 |
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