RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure
Henry, P. F., Hughes, R. W., Ward, S. C. and Weller, M. T. (2000) RbCuPO4 - a maximum copper tetrahedral framework adopting the zeotype ABW structure. Chemical Communications, (19), 1959-1960. (doi: 10.1039/b006429g).
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The sky blue RbCuPO4-ABW is the first reported maximum copper (framework ratio 1:1) zeotype framework, consisting of alternating PO4 and flattened CuO4 (Cu-O 1.89-1.95 Angstrom) tetrahedra; a second metastable very pale green-blue phase can also be produced by quenching, with conversion to the purely four-coordinate copper material accomplished by application of slight mechanical pressure.
|Keywords:||zeolite abw, phases|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||20 Dec 2005|
|Last Modified:||01 Jun 2011 16:07|
|Contributors:||Henry, P. F. (Author)
Hughes, R. W. (Author)
Ward, S. C. (Author)
Weller, M. T. (Author)
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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