Pyridine functionalised N-heterocyclic carbene complexes of palladium
Tulloch, A. A. D., Danopoulos, A. A., Tooze, R. P., Cafferkey, S. M., Kleinhenz, S. and Hursthouse, M. B. (2000) Pyridine functionalised N-heterocyclic carbene complexes of palladium. Chemical Communications, (14), 1247-1248. (doi: 10.1039/b002645j).
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Original Publication URL: http://www.rsc.org/Publishing/Journals/CC/article....
Description/Abstract
The pyridine functionalised N-heterocyclic carbene complexes (C-N)PdMeBr, C-N = 3-R-1-(2-picolyl)imidazolin-2-ylidene, (R = Bu-t 1a, R = mes 1b, mes = mesityl) are described; they are excellent catalysts for the Heck arylation; 1b is monomeric with a chelating C-N ligand; the product obtained by interaction of 1a with AgO2CCF3 shows a [Pd(C-N)](4) framework with bridging C-N ligands.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | olefin metathesis, catalysts |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 18933 |
| Date Deposited: | 20 Dec 2005 |
| Last Modified: | 01 Jun 2011 16:07 |
| Contributors: | Tulloch, A. A. D. (Author) Danopoulos, A. A. (Author) Tooze, R. P. (Author) Cafferkey, S. M. (Author) Kleinhenz, S. (Author) Hursthouse, M. B. (Author) |
| Date: | 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/18933 |
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