Pyridine functionalised N-heterocyclic carbene complexes of palladium

Tulloch, A. A. D., Danopoulos, A. A., Tooze, R. P., Cafferkey, S. M., Kleinhenz, S. and Hursthouse, M. B. (2000) Pyridine functionalised N-heterocyclic carbene complexes of palladium. Chemical Communications, (14), 1247-1248. (doi:10.1039/b002645j).


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The pyridine functionalised N-heterocyclic carbene complexes (C-N)PdMeBr, C-N = 3-R-1-(2-picolyl)imidazolin-2-ylidene, (R = Bu-t 1a, R = mes 1b, mes = mesityl) are described; they are excellent catalysts for the Heck arylation; 1b is monomeric with a chelating C-N ligand; the product obtained by interaction of 1a with AgO2CCF3 shows a [Pd(C-N)](4) framework with bridging C-N ligands.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b002645j
Related URLs:
Keywords: olefin metathesis, catalysts
Subjects: Q Science
Q Science > QD Chemistry
Divisions : University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18933
Accepted Date and Publication Date:
Date Deposited: 20 Dec 2005
Last Modified: 31 Mar 2016 11:35

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