A novel chiral distibine-centred polyimido anion
Coles, S. J., Hursthouse, M. B., Joy, J. S. and Paver, M. A. (2000) A novel chiral distibine-centred polyimido anion. Journal of the Chemical Society, Dalton Transactions, (19), 3239-3241. (doi: 10.1039/b007031i).
Download
Full text not available from this repository.
Original Publication URL: http://www.rsc.org/Publishing/Journals/DT/article....
Description/Abstract
Reaction of (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2) with 4 equivalents of 2-NHLiPy (Py = pyridyl) generates the novel distibine-centred dianion complex 1,3-[(RNLi)Sb](2)(mu-NR)(CH2)(3).(RNHLi). 3THF (1), incorporating the co-complexation of primary lithium amide; the X-ray crystal structure of 1 reveals a bimetallic imido-/amido-bridged cage structure of interlocking 6-membered rings, crystallising as a single enantiomer.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | complex |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 18945 |
| Date Deposited: | 20 Dec 2005 |
| Last Modified: | 01 Jun 2011 16:07 |
| Contributors: | Coles, S. J. (Author) Hursthouse, M. B. (Author) Joy, J. S. (Author) Paver, M. A. (Author) |
| Date: | 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/18945 |
Actions (login required)
 |
View Item |
