A novel chiral distibine-centred polyimido anion

Coles, S. J., Hursthouse, M. B., Joy, J. S. and Paver, M. A. (2000) A novel chiral distibine-centred polyimido anion. Journal of the Chemical Society, Dalton Transactions, (19), 3239-3241. (doi:10.1039/b007031i).


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Reaction of (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2) with 4 equivalents of 2-NHLiPy (Py = pyridyl) generates the novel distibine-centred dianion complex 1,3-[(RNLi)Sb](2)(mu-NR)(CH2)(3).(RNHLi). 3THF (1), incorporating the co-complexation of primary lithium amide; the X-ray crystal structure of 1 reveals a bimetallic imido-/amido-bridged cage structure of interlocking 6-membered rings, crystallising as a single enantiomer.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1039/b007031i
Related URLs:
Keywords: complex
Subjects: Q Science
Q Science > QD Chemistry
Divisions : University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18945
Accepted Date and Publication Date:
Date Deposited: 20 Dec 2005
Last Modified: 31 Mar 2016 11:35
URI: http://eprints.soton.ac.uk/id/eprint/18945

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