A novel chiral distibine-centred polyimido anion


Coles, S. J., Hursthouse, M. B., Joy, J. S. and Paver, M. A. (2000) A novel chiral distibine-centred polyimido anion. Journal of the Chemical Society, Dalton Transactions, (19), 3239-3241. (doi: 10.1039/b007031i).

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Description/Abstract

Reaction of (Me2N)(2)Sb(CH2)(3)Sb(NMe2)(2) with 4 equivalents of 2-NHLiPy (Py = pyridyl) generates the novel distibine-centred dianion complex 1,3-[(RNLi)Sb](2)(mu-NR)(CH2)(3).(RNHLi). 3THF (1), incorporating the co-complexation of primary lithium amide; the X-ray crystal structure of 1 reveals a bimetallic imido-/amido-bridged cage structure of interlocking 6-membered rings, crystallising as a single enantiomer.

Item Type: Article
Related URLs:
Keywords: complex
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18945
Date Deposited: 20 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18945

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