Neutron and X-ray powder diffraction studies of the oxynitrides SrW(O,N)(3), Ba3W2(O,N)(8) and Ba3Mo2(O,N)(8)
Weller, M. T. and Skinner, S. J. (2000) Neutron and X-ray powder diffraction studies of the oxynitrides SrW(O,N)(3), Ba3W2(O,N)(8) and Ba3Mo2(O,N)(8). International Journal of Inorganic Materials, 2, (5), 463-467. (doi:10.1016/S1466-6049(00)00032-5).
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Oxynitrides of composition SrW(O,N)(3), Ba3W2(O,N)(8) and Ba3Mo2(O,N)(8) have been prepared by the ammonolysis of stoichiometric mixtures of oxides and carbonates. Combined Rietveld refinements of powder neutron and powder X-ray diffraction data have allowed the structure of each to be determined. SrW(O,N)(3) was found to have a cubic Perovskite structure whereas Ba3W2(O,N)(8) and Ba3Mo2(O,N)(8) have a layered hexagonal structure. In the hexagonal structures the oxygen and nitrogen atoms are distributed almost randomly over two sites in the unit cell producing 4-fold co-ordination to tungsten and molybdenum, a distorted octahedral co-ordination to one barium site and a 10-fold co-ordination to the other.
|Digital Object Identifier (DOI):||doi:10.1016/S1466-6049(00)00032-5|
|Keywords:||nitrides, oxides, neutron scattering, crystal structure perovskite|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||19 Jan 2006|
|Last Modified:||31 Mar 2016 11:35|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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