Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)


Rashid, S., Turner, S. S., Day, P., Light, M. E. and Hursthouse, M. B. (2000) Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-). Inorganic Chemistry, 39, (11), 2426-2428. (doi: 10.1021/ic991409w).

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Description/Abstract

The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.

Item Type: Article
Related URLs:
Keywords: magnetic-properties, crystal-structure, superconductor, ions
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18963
Date Deposited: 17 Jan 2006
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18963

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