Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-)
Rashid, S., Turner, S. S., Day, P., Light, M. E. and Hursthouse, M. B. (2000) Molecular charge-transfer salt of BEDT-TTF bis(ethylenedithio)tetrathiafulvalene with the oxalate-bridged dimeric anion Fe-2(C2O4)(5) (4-). Inorganic Chemistry, 39, (11), 2426-2428. (doi: 10.1021/ic991409w).
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Description/Abstract
The compound (BEDT-TTF)(4). Fe-2(C2O4)(5) consists of an Fe-(III)-F-(III) oxalate bridged dimer, with a Fe-Fe distance of 5.472 Angstrom interspersed with 4 BEDT-TTF in a "checkerboard" arrangement It contains [Fe-2(C2O4)(5)](4-) anions and four dimerized BEDT-TTF cations each having an approximate charge of +1. The compound is semiconducting and exhibits short-range antiferromagnetic ordering at low temperature.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | magnetic-properties, crystal-structure, superconductor, ions |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 18963 |
| Date Deposited: | 17 Jan 2006 |
| Last Modified: | 31 May 2011 23:28 |
| Contributors: | Rashid, S. (Author) Turner, S. S. (Author) Day, P. (Author) Light, M. E. (Author) Hursthouse, M. B. (Author) |
| Date: | 29 May 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/18963 |
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