The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O


Muncaster, G., Sankar, G., Catlow, C. R. A., Thomas, J. M., Coles, S. J. and Hursthouse, M. (2000) The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O. Chemistry of Materials, 12, (1), 16-18. (doi: 10.1021/cm990500v).

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Description/Abstract

Crystal structure of (K5CoW12O40)-W-III. 20H(2)O is obtained from a detailed single-crystal study. The interatomic distance, in particular the Co(III)-O distance obtained from the present study is in close agreement with the Co K-edge EXAFS data of the title compound. This material will serve as a good model system for understanding the redox properties of microporous cobalt-substituted aluminophosphate catalysts, since the title compound is noted as a rare example of Co(III) in tetrahedral coordination.

Item Type: Article
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Keywords: molecular-sieve, redox centers, catalysts, cyclohexane, chemistry, lewis
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18981
Date Deposited: 18 Jan 2006
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18981

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