The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O
Muncaster, G., Sankar, G., Catlow, C. R. A., Thomas, J. M., Coles, S. J. and Hursthouse, M. (2000) The local structure of tetrahedral Co(III): A detailed crystal structure investigation of K5Co(III)W12O40 center dot 20H(2)O. Chemistry of Materials, 12, (1), 16-18. (doi:10.1021/cm990500v).
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Crystal structure of (K5CoW12O40)-W-III. 20H(2)O is obtained from a detailed single-crystal study. The interatomic distance, in particular the Co(III)-O distance obtained from the present study is in close agreement with the Co K-edge EXAFS data of the title compound. This material will serve as a good model system for understanding the redox properties of microporous cobalt-substituted aluminophosphate catalysts, since the title compound is noted as a rare example of Co(III) in tetrahedral coordination.
|Digital Object Identifier (DOI):||doi:10.1021/cm990500v|
|Keywords:||molecular-sieve, redox centers, catalysts, cyclohexane, chemistry, lewis|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||18 Jan 2006|
|Last Modified:||31 Mar 2016 11:35|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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