Insertion of metallated epoxynitriles into organozirconocene chlorides. A convergent synthesis of 2-cyano-1,3-dienes
Kasatkin, A. N. and Whitby, R. J. (2000) Insertion of metallated epoxynitriles into organozirconocene chlorides. A convergent synthesis of 2-cyano-1,3-dienes. Tetrahedron Letters, 41, (32), 6201-6205. (doi:10.1016/S0040-4039(00)01006-6).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(00)01006-6
Description/Abstract
Lithiated epoxynitriles insert efficiently into alkenylzirconocene chlorides via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(Cl)O- to afford substituted 2-cyano-1,3-dienes.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | zirconium, carbenoid, metallated epoxides, epoxynitrile, cyanodiene substituted epoxides, convenient synthesis, oxiranyl anions, reagents, lithiation, 2-cyano-1,3-butadienes, carbenoids, aldehydes, ketones |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 18999 |
| Date Deposited: | 15 Dec 2005 |
| Last Modified: | 01 Jun 2011 13:35 |
| Contributors: | Kasatkin, A. N. (Author) Whitby, R. J. (Author) |
| Date: | 5 August 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/18999 |
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