Insertion of metallated epoxynitriles into organozirconocene chlorides. A convergent synthesis of 2-cyano-1,3-dienes


Kasatkin, A. N. and Whitby, R. J. (2000) Insertion of metallated epoxynitriles into organozirconocene chlorides. A convergent synthesis of 2-cyano-1,3-dienes. Tetrahedron Letters, 41, (32), 6201-6205. (doi:10.1016/S0040-4039(00)01006-6).

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Description/Abstract

Lithiated epoxynitriles insert efficiently into alkenylzirconocene chlorides via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(Cl)O- to afford substituted 2-cyano-1,3-dienes.

Item Type: Article
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Keywords: zirconium, carbenoid, metallated epoxides, epoxynitrile, cyanodiene substituted epoxides, convenient synthesis, oxiranyl anions, reagents, lithiation, 2-cyano-1,3-butadienes, carbenoids, aldehydes, ketones
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 18999
Date Deposited: 15 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/18999

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