Insertion of metallated epoxides into zirconacycles

Kasatkin, A. N. and Whitby, R. J. (2000) Insertion of metallated epoxides into zirconacycles. Tetrahedron Letters, 41, (27), 5275-5280. (doi:10.1016/S0040-4039(00)00805-4).


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Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert efficiently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(R)O- to afford substituted alkenes.

Item Type: Article
Digital Object Identifier (DOI): doi:10.1016/S0040-4039(00)00805-4
Related URLs:
Keywords: zirconium, zirconacycles, silicon, nitriles, carbenoids, alkenes tandem insertion, lithium chloroallylide, substituted epoxides, zirconium chemistry, oxiranyl anions, aldehydes, reagents, ketones, lithiation, alkynes
Subjects: Q Science
Q Science > QD Chemistry
Divisions : University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19000
Accepted Date and Publication Date:
1 July 2000Published
Date Deposited: 15 Dec 2005
Last Modified: 31 Mar 2016 11:35

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