Insertion of metallated epoxides into zirconacycles
Kasatkin, A. N. and Whitby, R. J. (2000) Insertion of metallated epoxides into zirconacycles. Tetrahedron Letters, 41, (27), 5275-5280. (doi:10.1016/S0040-4039(00)00805-4).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(00)00805-4
Description/Abstract
Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert efficiently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(R)O- to afford substituted alkenes.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | zirconium, zirconacycles, silicon, nitriles, carbenoids, alkenes tandem insertion, lithium chloroallylide, substituted epoxides, zirconium chemistry, oxiranyl anions, aldehydes, reagents, ketones, lithiation, alkynes |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19000 |
| Date Deposited: | 15 Dec 2005 |
| Last Modified: | 01 Jun 2011 13:35 |
| Contributors: | Kasatkin, A. N. (Author) Whitby, R. J. (Author) |
| Date: | 1 July 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19000 |
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