Insertion of metallated epoxides into zirconacycles


Kasatkin, A. N. and Whitby, R. J. (2000) Insertion of metallated epoxides into zirconacycles. Tetrahedron Letters, 41, (27), 5275-5280. (doi:10.1016/S0040-4039(00)00805-4).

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Description/Abstract

Metallated epoxides (epoxysilanes, epoxynitriles, epoxystyrene) insert efficiently into zirconacycles via a 1,2-metallate rearrangement to form intermediates which eliminate Cp2Zr(R)O- to afford substituted alkenes.

Item Type: Article
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Keywords: zirconium, zirconacycles, silicon, nitriles, carbenoids, alkenes tandem insertion, lithium chloroallylide, substituted epoxides, zirconium chemistry, oxiranyl anions, aldehydes, reagents, ketones, lithiation, alkynes
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19000
Date Deposited: 15 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/19000

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