Hydrothermal synthesis of Co-3(TPO)(2)(bipy)(2)(H2O)(6).2.4H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer


Plater, M. J., Foreman, M. R. S., Gelbrich, T. and Hursthouse, M. B. (2000) Hydrothermal synthesis of Co-3(TPO)(2)(bipy)(2)(H2O)(6).2.4H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer. Journal of Chemical Crystallography, 30, (3), 155-158.

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Description/Abstract

An improved structure determination of the title compound 1 has been accomplished. It consists of infinite double stranded chains which resemble a molecular ladder. Two different octahedral cobalt ions are present which connect the strands together. There are 8.4 water molecules per formulae unit, 2.4 of which are noncoordinating. The structure has a triclinic space group P (1) over bar with a = 10.8655(7) Å,: b = 11.4362 (9) Å and c = 13.6684(9) Å; α = 111.181(7)°, β = 93.417(9)° and γ = 99.542(9)°; V = 1548.5(2) Å (3) and Z = 2.

Item Type: Article
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Keywords: coordination polymer, hydrothermal metal-organic framework, x-ray-diffraction, benzene-1,3,5-tricarboxylicacid, channels, network, binding, design, solids
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19007
Date Deposited: 18 Jan 2006
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/19007

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