Hydrothermal synthesis of Co-3(TPO)(2)(bipy)(2)(H2O)(6).2.4H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer
Hydrothermal synthesis of Co-3(TPO)(2)(bipy)(2)(H2O)(6).2.4H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer
An improved structure determination of the title compound 1 has been accomplished. It consists of infinite double stranded chains which resemble a molecular ladder. Two different octahedral cobalt ions are present which connect the strands together. There are 8.4 water molecules per formulae unit, 2.4 of which are noncoordinating. The structure has a triclinic space group P (1) over bar with a = 10.8655(7) Å,: b = 11.4362 (9) Å and c = 13.6684(9) Å; ? = 111.181(7)°, ? = 93.417(9)° and ? = 99.542(9)°; V = 1548.5(2) Å (3) and Z = 2.
coordination polymer, hydrothermal
metal-organic framework, x-ray-diffraction, benzene-1, 3, 5-tricarboxylicacid, channels, network, binding, design, solids
155-158
Plater, M. J.
3c5273d7-1076-4640-b49e-0d8d7727e4e0
Foreman, M. R. S.
83234065-a238-458d-a61e-8a7e09f3b38f
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
1 March 2000
Plater, M. J.
3c5273d7-1076-4640-b49e-0d8d7727e4e0
Foreman, M. R. S.
83234065-a238-458d-a61e-8a7e09f3b38f
Gelbrich, T.
6874d813-bf11-4950-b322-dfe77c533f41
Hursthouse, M. B.
57a2ddf9-b1b3-4f38-bfe9-ef2f526388da
Plater, M. J., Foreman, M. R. S., Gelbrich, T. and Hursthouse, M. B.
(2000)
Hydrothermal synthesis of Co-3(TPO)(2)(bipy)(2)(H2O)(6).2.4H2O (H3TPO = tris-(4-carboxylphenyl)phosphine oxide). A 1-D double stranded co-ordination polymer.
Journal of Chemical Crystallography, 30 (3), .
Abstract
An improved structure determination of the title compound 1 has been accomplished. It consists of infinite double stranded chains which resemble a molecular ladder. Two different octahedral cobalt ions are present which connect the strands together. There are 8.4 water molecules per formulae unit, 2.4 of which are noncoordinating. The structure has a triclinic space group P (1) over bar with a = 10.8655(7) Å,: b = 11.4362 (9) Å and c = 13.6684(9) Å; ? = 111.181(7)°, ? = 93.417(9)° and ? = 99.542(9)°; V = 1548.5(2) Å (3) and Z = 2.
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Published date: 1 March 2000
Keywords:
coordination polymer, hydrothermal
metal-organic framework, x-ray-diffraction, benzene-1, 3, 5-tricarboxylicacid, channels, network, binding, design, solids
Identifiers
Local EPrints ID: 19007
URI: http://eprints.soton.ac.uk/id/eprint/19007
ISSN: 1074-1542
PURE UUID: 165259d3-95bf-464a-b30d-92a779220f9c
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Date deposited: 18 Jan 2006
Last modified: 08 Jan 2022 12:50
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Contributors
Author:
M. J. Plater
Author:
M. R. S. Foreman
Author:
T. Gelbrich
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