Field-induced alignment of the directors in the smectic A phase. Experiment and simulation
Luckhurst, G. R. (2000) Field-induced alignment of the directors in the smectic A phase. Experiment and simulation. Molecular Crystals and Liquid Crystals, 347, 365-379.
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Description/Abstract
In contrast to nematics far less is known about the alignment of the directors in a smectic A phase by an external field. To characterise this process, which necessarily involves the flow of the molecules, we have undertaken an NMR investigation of the smectic A phase of 4-octyl-4'-cyanobiphenyl. The results of these experiments have revealed that, as expected, the alignment of the directors is a complex process strongly influenced by the nature of the containing surface for the smectic A phase. To assist in understanding the alignment process we have used computer simulations to study the field induced alignment of the directors in the smectic A phase formed by the Gay-Berne mesogen GB(4.4,20.0,1.1).
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | smectic a, director alignment, nmr, computer simulation |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19021 |
| Date Deposited: | 18 Jan 2006 |
| Last Modified: | 01 Jun 2011 16:07 |
| Contributors: | Luckhurst, G. R. (Author) |
| Date: | 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19021 |
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