A deuterium nuclear magnetic resonance investigation of field induced director dynamics in a nematic slab subject to magnetic and pulsed electric fields
Dunn, C. J., Luckhurst, G. R., Miyamoto, T., Naito, H., Sugimura, A. and Timimi, B. A. (2000) A deuterium nuclear magnetic resonance investigation of field induced director dynamics in a nematic slab subject to magnetic and pulsed electric fields. Molecular Crystals and Liquid Crystals, 347, 411-422.
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Deuterium nuclear magnetic resonance (NMR) spectroscopy has been used to investigate the field-induced director dynamics in a nematic liquid crystal, 4-pentyl-d(2)-4'-cyanobiphenyl (5CB-d(2)) deuteriated in the alpha -position of the pentyl chain, confined between two glass plates. The NMR spectra have been measured as a function of time after turning an electric field on and off It is demonstrated that the field-induced director dynamics in the nematic liquid crystal cells can be successfully time-resolved. In addition, it is found that the doubler NMR spectra become powder-like during the turn-on and rum-off processes. It is shown that the rotational viscosity and the diamagnetic anisotropy of 5CB-d(2) can be determined from the time-resolved NMR spectra by assuming uniform alignment of the director.
|Keywords:||director dynamics, rotational viscosity, diamagnetic anisotropy, deuterium nuclear magnetic resonanceliquid-crystal, behavior, nmr|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||18 Jan 2006|
|Last Modified:||01 Jun 2011 11:02|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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