Carbenoid insertion into alkenylzirconocenes - a convergent synthesis of functionalised allylmetallics


Kasatkin, A. N. and Whitby, R. J. (2000) Carbenoid insertion into alkenylzirconocenes - a convergent synthesis of functionalised allylmetallics. Tetrahedron Letters, 41, (32), 6211-6216. (doi:10.1016/S0040-4039(00)01024-8).

Download

Full text not available from this repository.

Description/Abstract

Insertion of lithium alkylcarbenoids RC(A)LiX, A= CN, P(O)(OEt)(2), SO2Ph, OMe into alkenylzirconocene chlorides derived by hydrozirconation of terminal alkynes affords functionalised allylzirconium reagents which may be further elaborated.

Item Type: Article
Related URLs:
Keywords: boronic esters, carbonyl-compounds, aldehydes, alpha, reagents, hydrozirconation, homologation, metals, regioselectivity, zirconacycles
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19063
Date Deposited: 15 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/19063

Actions (login required)

View Item View Item