Carbenoid insertion into alkenylzirconocenes - a convergent synthesis of functionalised allylmetallics
Kasatkin, A. N. and Whitby, R. J. (2000) Carbenoid insertion into alkenylzirconocenes - a convergent synthesis of functionalised allylmetallics. Tetrahedron Letters, 41, (32), 6211-6216. (doi:10.1016/S0040-4039(00)01024-8).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(00)01024-8
Description/Abstract
Insertion of lithium alkylcarbenoids RC(A)LiX, A= CN, P(O)(OEt)(2), SO2Ph, OMe into alkenylzirconocene chlorides derived by hydrozirconation of terminal alkynes affords functionalised allylzirconium reagents which may be further elaborated.
| Item Type: | Article |
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| Related URLs: | |
| Keywords: | boronic esters, carbonyl-compounds, aldehydes, alpha, reagents, hydrozirconation, homologation, metals, regioselectivity, zirconacycles |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19063 |
| Date Deposited: | 15 Dec 2005 |
| Last Modified: | 01 Jun 2011 13:35 |
| Contributors: | Kasatkin, A. N. (Author) Whitby, R. J. (Author) |
| Date: | 5 August 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19063 |
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