A biomimetic model reaction for the extradiol catechol dioxygenases
Lin, G., Reid, G. and Bugg, T. D. H. (2000) A biomimetic model reaction for the extradiol catechol dioxygenases. Chemical Communications, (13), 1119-1120. (doi: 10.1039/b003625k).
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Original Publication URL: http://www.rsc.org/Publishing/Journals/CC/article....
Description/Abstract
A model reaction is described for extradiol catechol cleavage involving FeCl2 or FeCl3, 1,4,9-triazacyclononane (TACN), pyridine and dioxygen which shows similar cofactor and regio-selectivity to the extradiol catechol dioxygenases.
| Item Type: | Article |
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| Related URLs: | |
| Keywords: | oxidative cleavage, functional-model, ring-cleavage, 1,2-dioxygenase, intermediate, complexes, mechanism, enzymes |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19071 |
| Date Deposited: | 20 Dec 2005 |
| Last Modified: | 01 Jun 2011 01:47 |
| Contributors: | Lin, G. (Author) Reid, G. (Author) Bugg, T. D. H. (Author) |
| Date: | 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19071 |
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