A biomimetic model reaction for the extradiol catechol dioxygenases


Lin, G., Reid, G. and Bugg, T. D. H. (2000) A biomimetic model reaction for the extradiol catechol dioxygenases. Chemical Communications, (13), 1119-1120. (doi: 10.1039/b003625k).

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Description/Abstract

A model reaction is described for extradiol catechol cleavage involving FeCl2 or FeCl3, 1,4,9-triazacyclononane (TACN), pyridine and dioxygen which shows similar cofactor and regio-selectivity to the extradiol catechol dioxygenases.

Item Type: Article
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Keywords: oxidative cleavage, functional-model, ring-cleavage, 1,2-dioxygenase, intermediate, complexes, mechanism, enzymes
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19071
Date Deposited: 20 Dec 2005
Last Modified: 27 Mar 2014 18:08
URI: http://eprints.soton.ac.uk/id/eprint/19071

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