A biomimetic model reaction for the extradiol catechol dioxygenases

Lin, G., Reid, G. and Bugg, T. D. H. (2000) A biomimetic model reaction for the extradiol catechol dioxygenases. Chemical Communications, (13), 1119-1120. (doi: 10.1039/b003625k)

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Official URL: http://www.rsc.org/Publishing/Journals/CC/article....

Description/Abstract

A model reaction is described for extradiol catechol cleavage involving FeCl2 or FeCl3, 1,4,9-triazacyclononane (TACN), pyridine and dioxygen which shows similar cofactor and regio-selectivity to the extradiol catechol dioxygenases.

Item Type:Article
Uncontrolled Keywords:oxidative cleavage, functional-model, ring-cleavage, 1,2-dioxygenase, intermediate, complexes, mechanism, enzymes
Related URLs:http://www.rsc.org/Publishing/...i=b003625k
Subjects:Q Science
Q Science > QD Chemistry
Divisions:University Structure - Pre August 2011 > School of Chemistry
ePrint ID:19071
URI:http://eprints.soton.ac.uk/id/eprint/19071
Deposited On:20 Dec 2005
Last Modified:01 Jun 2011 02:47

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