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A biomimetic model reaction for the extradiol catechol dioxygenases

A biomimetic model reaction for the extradiol catechol dioxygenases
A biomimetic model reaction for the extradiol catechol dioxygenases
A model reaction is described for extradiol catechol cleavage involving FeCl2 or FeCl3, 1,4,9-triazacyclononane (TACN), pyridine and dioxygen which shows similar cofactor and regio-selectivity to the extradiol catechol dioxygenases.
oxidative cleavage, functional-model, ring-cleavage, 1, 2-dioxygenase, intermediate, complexes, mechanism, enzymes
1359-7345
1119-1120
Lin, G.
09f605b7-7804-457c-b58f-aa605eab0c34
Reid, G.
ff85ed93-1d4e-4c2b-a9b7-d927a61c4abe
Bugg, T. D. H.
a1d6d985-d7ba-408d-a4d1-9bfa0c0642bf
Lin, G.
09f605b7-7804-457c-b58f-aa605eab0c34
Reid, G.
ff85ed93-1d4e-4c2b-a9b7-d927a61c4abe
Bugg, T. D. H.
a1d6d985-d7ba-408d-a4d1-9bfa0c0642bf

Lin, G., Reid, G. and Bugg, T. D. H. (2000) A biomimetic model reaction for the extradiol catechol dioxygenases. Chemical Communications, (13), 1119-1120. (doi:10.1039/b003625k).

Record type: Article

Abstract

A model reaction is described for extradiol catechol cleavage involving FeCl2 or FeCl3, 1,4,9-triazacyclononane (TACN), pyridine and dioxygen which shows similar cofactor and regio-selectivity to the extradiol catechol dioxygenases.

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More information

Published date: 2000
Keywords: oxidative cleavage, functional-model, ring-cleavage, 1, 2-dioxygenase, intermediate, complexes, mechanism, enzymes

Identifiers

Local EPrints ID: 19071
URI: http://eprints.soton.ac.uk/id/eprint/19071
ISSN: 1359-7345
PURE UUID: c8514864-a48f-4d22-a344-9ab8d42c1c61

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Date deposited: 20 Dec 2005
Last modified: 15 Mar 2024 06:10

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Contributors

Author: G. Lin
Author: G. Reid
Author: T. D. H. Bugg

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