Acetoacetoxy ethyl methacrylate (AAEM) resin, a new scavenger for primary amines in the presence of secondary amines
Yu, Z. R., Alesso, S., Pears, D., Worthington, P. A., Luke, R. W. A. and Bradley, M. (2000) Acetoacetoxy ethyl methacrylate (AAEM) resin, a new scavenger for primary amines in the presence of secondary amines. Tetrahedron Letters, 41, (46), 8963-8967. (doi:10.1016/S0040-4039(00)01590-2).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(00)01590-2
Description/Abstract
Preliminary results on a new type of polymer scavenger, acetoacetoxy ethyl methacrylate (AAEM) resin, are reported. AAEM resin can selectively remove primary amines in the presence of secondary amines. Its application in a solution library synthesis is demonstrated.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | combinatorial chemistry, reductive alkylation, polymer scavenger, amines small-molecule libraries, reductive amination, sodiumtriacetoxyborohydride, chemoselective reductions, solution-phase, purification, ketones, aldehydes, borohydride, reagents |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19075 |
| Date Deposited: | 15 Dec 2005 |
| Last Modified: | 01 Jun 2011 13:35 |
| Contributors: | Yu, Z. R. (Author) Alesso, S. (Author) Pears, D. (Author) Worthington, P. A. (Author) Luke, R. W. A. (Author) Bradley, M. (Author) |
| Date: | 11 November 2000 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19075 |
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