X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex


Stulz, Eugen and Leumann, Christian (1999) X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex. Chemical Communications, (3), 239-240. (doi:10.1039/a809101c).

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Description/Abstract

The X-ray structure of the complex Zr-IV(acac)(2)(salicylideneaminoethanol) [Zr(acac)(2)(sae)] could be solved, and the reactivity of the complex towards phosphate diester solvolysis was investigated showing substantial rate acceleration over background in benzene-methanol solution (ca. 10(8)) and in aqueous medium (ca. 10(5)).

Item Type: Article
ISSNs: 1359-7345 (print)
1364-548X (electronic)
Subjects: Q Science > QD Chemistry
Q Science > QH Natural history > QH301 Biology
T Technology > TP Chemical technology
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 191673
Date Deposited: 23 Jun 2011 13:05
Last Modified: 27 Mar 2014 19:43
URI: http://eprints.soton.ac.uk/id/eprint/191673

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