X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex
Stulz, Eugen and Leumann, Christian (1999) X-Ray structure and solvolytic activity towards phosphate diesters of a zirconium(IV) complex. Chemical Communications, (3), 239-240. (doi:10.1039/a809101c).
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Description/Abstract
The X-ray structure of the complex Zr-IV(acac)(2)(salicylideneaminoethanol) [Zr(acac)(2)(sae)] could be solved, and the reactivity of the complex towards phosphate diester solvolysis was investigated showing substantial rate acceleration over background in benzene-methanol solution (ca. 10(8)) and in aqueous medium (ca. 10(5)).
| Item Type: | Article |
|---|---|
| ISSNs: | 1359-7345 (print) 1364-548X (electronic) |
| Subjects: | Q Science > QD Chemistry Q Science > QH Natural history > QH301 Biology T Technology > TP Chemical technology |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 191673 |
| Date Deposited: | 23 Jun 2011 13:05 |
| Last Modified: | 23 Jun 2011 13:05 |
| Contributors: | Stulz, Eugen (Author) Leumann, Christian (Author) |
| Date: | 1 January 1999 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/191673 |
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