Phosphine-substituted porphyrins as supramolecular building blocks
Phosphine-substituted porphyrins as supramolecular building blocks
A route to alkyne-phosphine-substituted metalloporphyrins is presented. The X-ray structure of the methanol adduct of a diphenylphosphine Zn(II) porphyrin reveals solid state dimerisation accompanied by proton transfer from coordinated methanol to phosphine in a process reminiscent of carbonic anhydrase, The ability of the phosphine-substituted porphyrins to form non-covalent arrays with a Ru(II) porphyrin was explored using H-1/P-31 NMR and UV/vis spectroscopy as well as MALDI-TOF mass spectrometry.
261-264
Darling, Scott L.
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Stulz, Eugen
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Feeder, Neil
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Bampos, Nick
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Sanders, Jeremy K.M.
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18 April 2000
Darling, Scott L.
fbef4b54-4f6b-4528-adcd-987af79826e1
Stulz, Eugen
9a6c04cf-32ca-442b-9281-bbf3d23c622d
Feeder, Neil
f72b9f0c-f7a0-4d4a-9aa0-4654bd85c386
Bampos, Nick
a1d45344-d932-49c7-89ab-34ccd1d659aa
Sanders, Jeremy K.M.
a676d635-3196-437a-b894-a2bc5f857ae2
Darling, Scott L., Stulz, Eugen, Feeder, Neil, Bampos, Nick and Sanders, Jeremy K.M.
(2000)
Phosphine-substituted porphyrins as supramolecular building blocks.
New Journal of Chemistry, 24 (5), .
(doi:10.1039/b000482k).
Abstract
A route to alkyne-phosphine-substituted metalloporphyrins is presented. The X-ray structure of the methanol adduct of a diphenylphosphine Zn(II) porphyrin reveals solid state dimerisation accompanied by proton transfer from coordinated methanol to phosphine in a process reminiscent of carbonic anhydrase, The ability of the phosphine-substituted porphyrins to form non-covalent arrays with a Ru(II) porphyrin was explored using H-1/P-31 NMR and UV/vis spectroscopy as well as MALDI-TOF mass spectrometry.
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Published date: 18 April 2000
Identifiers
Local EPrints ID: 191677
URI: http://eprints.soton.ac.uk/id/eprint/191677
ISSN: 1144-0546
PURE UUID: 86a2be11-99c7-4bb6-a285-ef7e9aed2d15
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Date deposited: 23 Jun 2011 12:59
Last modified: 15 Mar 2024 03:26
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Contributors
Author:
Scott L. Darling
Author:
Neil Feeder
Author:
Nick Bampos
Author:
Jeremy K.M. Sanders
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