Photolysis of (Me2Si)(6) in argon matrices doped with high concentrations (ca. 20%) of N2O or C2H4O: formation of (Me2SiO)(6)
Almond, M. J., Cannady, J. P., Darling, T. A., Ogden, J. S. and Walsh, R. (2001) Photolysis of (Me2Si)(6) in argon matrices doped with high concentrations (ca. 20%) of N2O or C2H4O: formation of (Me2SiO)(6). Journal of Organometallic Chemistry, 640, (1-2), 177-181. (doi:10.1016/S0022-328X(01)01184-6).
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Irradiation using a low pressure mercury lamp (lambda =ca. 250 nm) of argon matrices containing ca. 1% (Me2Si)(6) and ca. 20% ethylene oxide (C2H4O) or nitrous oxide (N2O) for a period of ca. 20 h leads to the formation of the cyclic compound (Me2SiO)(6). This has a 12-membered ring with alternating Si and O atoms. It is identified by comparison of its infrared spectrum with a spectrum of an authentic sample. The reaction appears to proceed by stepwise insertion of O atoms into Si-Si bonds.
|Digital Object Identifier (DOI):||doi:10.1016/S0022-328X(01)01184-6|
|Keywords:||photolysis, matrix isolation, (me2si)(6), oxidation isolated dimethylsilylene, dodecamethylcyclohexasilane, photooxidation, 1-methylsilene|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||13 Feb 2006|
|Last Modified:||06 Aug 2015 02:18|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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