Photolysis of (Me2Si)(6) in argon matrices doped with high concentrations (ca. 20%) of N2O or C2H4O: formation of (Me2SiO)(6)
Almond, M. J., Cannady, J. P., Darling, T. A., Ogden, J. S. and Walsh, R. (2001) Photolysis of (Me2Si)(6) in argon matrices doped with high concentrations (ca. 20%) of N2O or C2H4O: formation of (Me2SiO)(6). Journal of Organometallic Chemistry, 640, (1-2), 177-181. (doi:10.1016/S0022-328X(01)01184-6)
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Official URL: http://dx.doi.org/10.1016/S0022-328X(01)01184-6
Description/Abstract
Irradiation using a low pressure mercury lamp (lambda =ca. 250 nm) of argon matrices containing ca. 1% (Me2Si)(6) and ca. 20% ethylene oxide (C2H4O) or nitrous oxide (N2O) for a period of ca. 20 h leads to the formation of the cyclic compound (Me2SiO)(6). This has a 12-membered ring with alternating Si and O atoms. It is identified by comparison of its infrared spectrum with a spectrum of an authentic sample. The reaction appears to proceed by stepwise insertion of O atoms into Si-Si bonds.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | photolysis, matrix isolation, (me2si)(6), oxidation isolated dimethylsilylene, dodecamethylcyclohexasilane, photooxidation, 1-methylsilene |
| Related URLs: | http://dx.doi.org/10.1016/S002...01)01184-6 |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19378 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19378 |
| Deposited On: | 13 Feb 2006 |
| Last Modified: | 01 Apr 2012 01:55 |
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