Organophosphoryl adducts of tris(pentafluorophenyl)borane; crystal and molecular structure of B(C6F5)(3)·Ph3PO
Beckett, Michael A., Brassington, David S., Light, Mark E. and Hursthouse, Michael B. (2001) Organophosphoryl adducts of tris(pentafluorophenyl)borane; crystal and molecular structure of B(C6F5)(3)·Ph3PO. Journal of the Chemical Society, Dalton Transactions, (11), 1768-1772. (doi: 10.1039/b100981h)
Download
Full text not available from this repository.
Official URL: http://dx.doi.org/10.1039/b100981h
Description/Abstract
A series of 1 : 1 adducts of B(C6F5)(3) with the organophosphoryl ligands Et3PO, Ph3PO, (Pr3PO)-P-n, Oct(3)(n)PO, (MeO)(3)PO, (EtO)(3)PO, (PhO)(3)PO, (EtO)(2)(H)PO, ((BuO)-O-n)(2)(H)PO, (PhO)(2)(H)PO, (MeO)(2)MePO, (EtO)(2)MePO, (EtO)(2)PhPO, and (EtO)Me2PO have been synthesized and characterised by elemental analysis, mp, and spectroscopic (H-1, C-13, B-11, F-19, P-31 NMR and IR) methods. B(C6F5)(3). Ph3PO was further characterised in the solid state by a single-crystal X-ray diffraction study. P-31 NMR chemical shifts and nu (PO) IR stretching frequencies are discussed in relation to substituent at phosphorus.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | lewis-acid tris(pentafluorophenyl)borane, phosphine, h2o-center-dot-b(c6f5)(3), b(c6f5)(3), complexes |
| Related URLs: | http://dx.doi.org/10.1039/b100981h |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19400 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19400 |
| Deposited On: | 14 Feb 2006 |
| Last Modified: | 01 Jun 2011 02:47 |
Associated Staff Only: edit my ePrint
