Isolation and characterisation of bis(oxahomo)fullerene derivatives of C60F18
Boltalina, Olga V., de La Vaissière, Benoît, Lukonin, Andrei Yu., Fowler, Patrick W., Abdul-Sada, Ala'a K., Street, Joan M. and Taylor, Roger (2001) Isolation and characterisation of bis(oxahomo)fullerene derivatives of C60F18. Journal of the Chemical Society, Perkin Transactions 2, (4), 550-556. (doi: 10.1039/b007935i)
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Official URL: http://dx.doi.org/10.1039/b007935i
Description/Abstract
From the products of the reaction of [60]fullerene with K2PtF6 under vacuum at 465 degreesC we have isolated seven isomers of C60F18O2, and characterized them by EI mass spectrometry, IR and F-19 NMR spectroscopy (both 1 D and 2 D). Comparison with data for mono-oxides and the observed lack of connectivity between the fluorines attached to carbons adjacent to oxygen, indicate that these compounds are diethers with oxygen inserted between fluorinated carbons. Structures proposed on the basis of the NMR spectra and semiempirical calculations are found to be consistent with HPLC retention times.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | fullerene, c-60, bisazafulleroids |
| Related URLs: | http://dx.doi.org/10.1039/b007935i |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19416 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19416 |
| Deposited On: | 14 Feb 2006 |
| Last Modified: | 01 Jun 2011 04:55 |
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