mer-Bis{2,6-bis 1-(4-tert-butylphenylimino)ethyl -pyridine}zinc(II) bis tris(hexafluoroacetylacetonato)zincate(II) diethyl ether hemisolvate
Coles, S. J., Granifo, J., Hursthouse, M. B. and Osborne, A. G. (2001) mer-Bis{2,6-bis 1-(4-tert-butylphenylimino)ethyl -pyridine}zinc(II) bis tris(hexafluoroacetylacetonato)zincate(II) diethyl ether hemisolvate. Acta Crystallographica Section E: Structure Reports Online, 57, (12), M535-M537. (doi:10.1107/S1600536801015458).
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Description/Abstract
Reaction of [Zn(hfac)(2)]. 2H(2)O with L-1, where hfac and L-1 are hexafluoroacetylacetonate and 2,6-bis[1-(4-tert-butylphenylimino)ethyl]pyridine, respectively, results in the formation of [Zn(L-1)(2)][Zn(hfac)(3)](2), i.e. [Zn(C29H35N3)(2)][Zn(C5HF6O2)(3)](2). -0.5C(4)H(10)O. In the cation, the two L-1 ligands act as merterdentate ligands. Reaction of [Zn(hfac)(2)]. 2H(2)O with 2,2':6',2 " -terpyridine (terpy) results in the formation of [Zn(terpy)(2)](hfac)(2).
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | molecular-structures, metal-ions, complexes |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19452 |
| Date Deposited: | 15 Feb 2006 |
| Last Modified: | 01 Jun 2011 01:48 |
| Contributors: | Coles, S. J. (Author) Granifo, J. (Author) Hursthouse, M. B. (Author) Osborne, A. G. (Author) |
| Date: | 1 November 2001 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19452 |
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