4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one


Coles, S. J. and Hursthouse, M. B. (2001) 4,8-Bis(3,4-methylenedioxy)phenyl-3,7-dioxabi-cyclo 3.3.0 octan-2-one. Acta Crystallographica Section E-Structure Reports Online, 57, (6), o544-o546. (doi:10.1107/S1600536801007437).

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Description/Abstract

The title compound, C20H16O7, is an intermediate in the total synthesis of (+/-)-asarinin. The molecular structure contains four chiral centres and crystallizes as two independent molecules. The chirality of the two molecules is the same, but they adopt different conformations. The compound is enantiomeric, with the second enantiomer arising from the centrosymmetric nature of the space group.

Item Type: Article
Related URLs:
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19456
Date Deposited: 15 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19456

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