Palladium-catalysed nucleophilic release of allylic amines from a phenolic resin
Fisher, M. and Brown, R. C. D. (2001) Palladium-catalysed nucleophilic release of allylic amines from a phenolic resin. Tetrahedron Letters, 42, (46), 8227-8230. (doi:10.1016/S0040-4039(01)01739-7).
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2 circle Allylic alcohols were coupled to phenolic polystyrene resin under Mitsunobu conditions to provide substituted allyl ethers. which underwent efficient nucleophilic cleavage by 1 degrees and 2 degrees amines in the presence of catalytic palladium to afford allylic amines.
|Keywords:||solid-phase synthesis, organic-synthesis, combinatorial chemistry, linkers|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||14 Feb 2006|
|Last Modified:||27 Mar 2014 18:09|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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