Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes


Grossel, Martin C., Golden, Christopher A., Gomm, John R., Horton, Peter N., Merckel, Daniel A.S., Oszer, Mustafa E. and Parker, Robert A. (2001) Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes. CrystEngComm, 3, 170-173. (doi:10.1039/b107221h).

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Original Publication URL: http://dx.doi.org/10.1039/b107221h

Description/Abstract

In the solid state, diesters of pyridine-2,6-dicarboxylic acid assemble into edge-to-edge, front-to-back associated tapes involving a novel triple supramolecular contact consisting of one N-pyridine***H-C-pyridine and two C=O***H-C-pyridine interactions. This intermolecular contact is robust, proving insensitive to additional interactions involving the side arms, and is also observed when the orientation of the pyridine core is reversed.

Item Type: Article
Related URLs:
Keywords: intermolecular interactions, hydrogen-bonds, complexes, chemistry, synthons, halogen
Subjects: T Technology > TP Chemical technology
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19497
Date Deposited: 15 Feb 2006
Last Modified: 27 Mar 2014 18:09
Contact Email Address: mcg1@soton.ac.uk
URI: http://eprints.soton.ac.uk/id/eprint/19497

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