Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes
Grossel, Martin C., Golden, Christopher A., Gomm, John R., Horton, Peter N., Merckel, Daniel A.S., Oszer, Mustafa E. and Parker, Robert A. (2001) Solid-state behaviour of pyridine-2,6-dicarboxylate esters: supramolecular assembly into infinite tapes. CrystEngComm, 3, 170-173. (doi:10.1039/b107221h).
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Description/Abstract
In the solid state, diesters of pyridine-2,6-dicarboxylic acid assemble into edge-to-edge, front-to-back associated tapes involving a novel triple supramolecular contact consisting of one N-pyridine***H-C-pyridine and two C=O***H-C-pyridine interactions. This intermolecular contact is robust, proving insensitive to additional interactions involving the side arms, and is also observed when the orientation of the pyridine core is reversed.
| Item Type: | Article |
|---|---|
| Related URLs: | |
| Keywords: | intermolecular interactions, hydrogen-bonds, complexes, chemistry, synthons, halogen |
| Subjects: | T Technology > TP Chemical technology |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19497 |
| Date Deposited: | 15 Feb 2006 |
| Last Modified: | 01 Jun 2011 08:32 |
| Contributors: | Grossel, Martin C. (Author) Golden, Christopher A. (Author) Gomm, John R. (Author) Horton, Peter N. (Author) Merckel, Daniel A.S. (Author) Oszer, Mustafa E. (Author) Parker, Robert A. (Author) |
| Date: | 2001 |
| Status: | Published |
| Contact Email Address: | mcg1@soton.ac.uk |
| URI: | http://eprints.soton.ac.uk/id/eprint/19497 |
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