Rational design of open-framework coordination solids - Synthesis and structure of Co-5(OH)(2){1,2,4,5-(O2C)(4)C6H2}(2)(H2O)(4) • xH(2)O


Gutschke, Siegfried O.H., Price, Daniel J., Powell, Annie K. and Wood, Paul T. (2001) Rational design of open-framework coordination solids - Synthesis and structure of Co-5(OH)(2){1,2,4,5-(O2C)(4)C6H2}(2)(H2O)(4) • xH(2)O. European Journal of Inorganic Chemistry, (11), 2739-2741. (doi: 10.1002/1099-0682(200111)2001:11<2739::AID-EJIC2739>3.0.CO;2-1).

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Description/Abstract

A strategy for preparing open-framework coordination solids by hydrothermal synthesis has been developed and tested by the synthesis of a new porous cobalt carboxylate which can be dehydrated by heating to give a material with coordinatively unsaturated metal ions.

Item Type: Article
ISSNs: 1434-1948 (print)
Related URLs:
Keywords: synthesis design, cobalt, carboxylate ligands, mesoporous materials cobalt phosphate, metal, catalysts, carboxylate, micropores, oxidation, complexes, reduction, polymer, binding
Subjects: Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
Item ID: 19499
Date Deposited: 16 Feb 2006
Last Modified: 31 May 2011 23:28
Contributors: Gutschke, Siegfried O.H. (Author)
Price, Daniel J. (Author)
Powell, Annie K. (Author)
Wood, Paul T. (Author)
Date: 1 November 2001
Status: Published
URI: http://eprints.soton.ac.uk/id/eprint/19499

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