A new cascade radical reaction for the synthesis of biaryls and triaryls from benzyl iodoaryl ethers
Harrowven, D. C., Nunn, M. I. T., Newman, N. A. and Fenwick, D. R. (2001) A new cascade radical reaction for the synthesis of biaryls and triaryls from benzyl iodoaryl ethers. Tetrahedron Letters, 42, (5), 961-964. (doi:10.1016/S0040-4039(00)02111-0).
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Original Publication URL: http://dx.doi.org/10.1016/S0040-4039(00)02111-0
Description/Abstract
The paper describes a new method of synthesizing biaryls and triaryls through an intramolecular ipso-substitution reaction initiated by the addition of an aryl radical to a benzyl ether. A tandem variant of the reaction has also been demonstrated. A short synthesis of isoaucuparin 27, a natural product found in the sapwood tissue of Sorbus aucuparia, is also described.
| Item Type: | Article |
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| Related URLs: | |
| Keywords: | radicals and radical reactions, natural products, aromatic chemistry, cascade reactionscondensed thiophenes |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| Item ID: | 19507 |
| Date Deposited: | 14 Feb 2006 |
| Last Modified: | 01 Jun 2011 11:02 |
| Contributors: | Harrowven, D. C. (Author) Nunn, M. I. T. (Author) Newman, N. A. (Author) Fenwick, D. R. (Author) |
| Date: | 29 January 2001 |
| Status: | Published |
| URI: | http://eprints.soton.ac.uk/id/eprint/19507 |
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