Intramolecular radical additions to quinolines


Harrowven, D. C., Sutton, B. J. and Coulton, S. (2001) Intramolecular radical additions to quinolines. Tetrahedron Letters, 42, (15), 2907-2910. (doi:10.1016/S0040-4039(01)00321-5).

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Description/Abstract

This paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines, was observed (implicating the so called oxidative tin hydride pathway).

Item Type: Article
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Keywords: radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationtert-butylmercury halides, condensed thiophenes, cyclizations, butylation, bu3snh
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19509
Date Deposited: 14 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19509

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