Intramolecular radical additions to quinolines
Harrowven, D. C., Sutton, B. J. and Coulton, S. (2001) Intramolecular radical additions to quinolines. Tetrahedron Letters, 42, (15), 2907-2910. (doi:10.1016/S0040-4039(01)00321-5).
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This paper is concerned with intramolecular radical additions to quinolines. Radical additions to C-2, C-3 and C-4 of a quinoline have all been shown to proceed under neutral conditions. In each case formation of heteroaromatic products, rather than dihydroquinolines, was observed (implicating the so called oxidative tin hydride pathway).
|Keywords:||radicals and radical reactions, quinolines, nitrogen heterocycles, cyclisationtert-butylmercury halides, condensed thiophenes, cyclizations, butylation, bu3snh|
Q Science > QD Chemistry
|Divisions:||University Structure - Pre August 2011 > School of Chemistry
|Date Deposited:||14 Feb 2006|
|Last Modified:||27 Mar 2014 18:09|
|RDF:||RDF+N-Triples, RDF+N3, RDF+XML, Browse.|
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