A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement
Khan, T., Skabara, P. J., Coles, S. J. and Hursthouse, M. B. (2001) A novel route towards formylated 1,3-dithiole-2-thiones via an unprecedented allylic 1,4-diol rearrangement. Chemical Communications, (4), 369-370. (doi: 10.1039/b009550h)
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Description/Abstract
In the presence of perchloric acid, an unusual 1,4-aryl shift is observed for two electron-rich 4,5-bis[hydroxy(aryl)methyl]-1,3-dithiole-2-thiones; the X-ray crystal structure of compound 8 confirms the structural identity of the rearrangement product.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | chemistry |
| Related URLs: | http://www.rsc.org/Publishing/...i=b009550h |
| Subjects: | Q Science Q Science > QD Chemistry |
| Divisions: | University Structure - Pre August 2011 > School of Chemistry |
| ePrint ID: | 19531 |
| URI: | http://eprints.soton.ac.uk/id/eprint/19531 |
| Deposited On: | 14 Feb 2006 |
| Last Modified: | 01 Jun 2011 14:37 |
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