Synthesis and properties of the first series of mixed thioether/telluroether macrocycles


Levason, W., Orchard, S. D. and Reid, G. (2001) Synthesis and properties of the first series of mixed thioether/telluroether macrocycles. Chemical Communications, (5), 427-428. (doi: 10.1039/b008370o).

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Description/Abstract

The preparations of the first examples of mixed thioether/telluroether macrocycles, [9]aneS(2)Te (1,4-dithia-7-telluracyclononane), [11]aneS(2)Te (1,4-dithia-8-telluracycloundecane), [12]aneS(2)Te (1,5-dithia-9-telluracyclododecane) and [14]aneS(3)Te (1,4,7-trithia-11-telluracyclotetradecane) via a 'disguised dilution' method are described, together with the crystal structure of [Ag([11]aneS(2)Te)]BF4 which serves to authenticate the macrocyclic ligand.

Item Type: Article
Related URLs:
Keywords: ditelluroether complexes, crystal-structures, ligands
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19547
Date Deposited: 14 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19547

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