Synthesis and properties of the first series of mixed thioether/telluroether macrocycles

Levason, W., Orchard, S. D. and Reid, G. (2001) Synthesis and properties of the first series of mixed thioether/telluroether macrocycles. Chemical Communications, (5), 427-428. (doi: 10.1039/b008370o)

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Description/Abstract

The preparations of the first examples of mixed thioether/telluroether macrocycles, [9]aneS(2)Te (1,4-dithia-7-telluracyclononane), [11]aneS(2)Te (1,4-dithia-8-telluracycloundecane), [12]aneS(2)Te (1,5-dithia-9-telluracyclododecane) and [14]aneS(3)Te (1,4,7-trithia-11-telluracyclotetradecane) via a 'disguised dilution' method are described, together with the crystal structure of [Ag([11]aneS(2)Te)]BF4 which serves to authenticate the macrocyclic ligand.

Item Type:Article
Uncontrolled Keywords:ditelluroether complexes, crystal-structures, ligands
Related URLs:http://www.rsc.org/Publishing/...i=b008370o
Subjects:Q Science
Q Science > QD Chemistry
Divisions:University Structure - Pre August 2011 > School of Chemistry
ePrint ID:19547
URI:http://eprints.soton.ac.uk/id/eprint/19547
Deposited On:14 Feb 2006
Last Modified:01 Jun 2011 04:55

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