(1S*,4S*,5R*,8R*)-8-(3,4-Dimethoxyphenyl)-4-(3,4,5-trimethoxyphenyl)-3,7 -dioxabicyclo 3.3.0 octan-2-one


Light, M. E. and Hursthouse, M. B. (2001) (1S*,4S*,5R*,8R*)-8-(3,4-Dimethoxyphenyl)-4-(3,4,5-trimethoxyphenyl)-3,7 -dioxabicyclo 3.3.0 octan-2-one. Acta Crystallographica Section E-Structure Reports Online, 57, (6), o514-o515. (doi:10.1107/S1600536801007425).

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Description/Abstract

The X-ray study of the title compound, C23H26O8, (I), confirmed the endo,exo-furofuranone structure of the important intermediate compound in the process of the total synthesis of (+/-)-epimagnolin A, which employs a new approach involving a highly diastereoselective CDH insertion reaction [Brown et al. (2001). Tetrahedron Lett. 42, 473-475].

Item Type: Article
Related URLs:
Subjects: Q Science
Q Science > QD Chemistry
Divisions: University Structure - Pre August 2011 > School of Chemistry
ePrint ID: 19557
Date Deposited: 15 Feb 2006
Last Modified: 27 Mar 2014 18:09
URI: http://eprints.soton.ac.uk/id/eprint/19557

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